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Lecture Organic chemistry: Chapter 2 - L. G. Wade, Jr.
Chapter 2 - Structure and properties of organic molecules. To understand these aspects of molecular structure we need to consider how the atomic orbitals on an atom mix to form hybrid atomic orbitals and how orbitals on different atoms combine to form molecular orbitals. In this chapter, we look more closely at how combinations of orbitals account for the shapes and properties we observe in organic molecules.
46 p dnulib 27/06/2019 229 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Wave properties of electrons, Wave interactions
Lecture Organic chemistry: Chapter 10 - L. G. Wade, Jr.
Alcohols are synthesized by a wide variety of methods, and the hydroxyl group may be converted to most other functional groups. For these reasons, alcohols are versatile synthetic intermediates. In this chapter, we discuss the physical properties of alcohols and summarize the methods used to synthesize them.
52 p dnulib 27/06/2019 127 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Synthesis of Alcohols, Structure of Alcohols
Lecture Organic chemistry: Chapter 9 - L. G. Wade, Jr.
Chapter 9 introduce to Alkynes. In this chapter, students will be able to: Draw and name alkynes, cycloalkynes, and their derivatives; show how to synthesize alkynes by eliminations from alkyl halides and by the additions and substitutions of acetylide ions; predict the products of the reactions of alkynes, including the orientation of the reaction (regiochemistry) and the stereochemistry;...
46 p dnulib 27/06/2019 143 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Acidity of Alkynes, Acetylide ions
Lecture Organic chemistry: Chapter 4 - L. G. Wade, Jr.
Chapter 4 - The Study of chemical reactions. In this chapter, students will be able to: Propose mechanisms and explain the steps for simple reactions such as free-radical halogenation; draw a reaction-energy diagram, and use it to identify the factors controlling the thermodynamics and kinetics of a reaction; use the mechanism, thermodynamics, and kinetics of a reaction to predict which of several possible products is the major product;...
54 p dnulib 27/06/2019 140 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Chemical reactions, Chlorination of Methane
Lecture Organic chemistry: Chapter 5 - L. G. Wade, Jr.
In this chapter, we study the three-dimensional structures of molecules to understand their stereochemical relationships. We compare the various types of stereoisomers and study ways to differentiate among stereoisomers. In future chapters, we will see how stereochemistry plays a major role in the properties and reactions of organic compounds.
48 p dnulib 27/06/2019 244 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Chiral carbons, Nonmobile conformers
Lecture Organic chemistry: Chapter 11 - L. G. Wade, Jr.
Chapter 11 - Reactions of Alcohols. Alcohols are important organic compounds because the hydroxyl group is easily converted to almost any other functional group. In Chapter 10, we studied reactions that form alcohols. In this chapter, we seek to understand how alcohols react and which reagents are best for converting them to other kinds of compounds.
53 p dnulib 27/06/2019 256 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Reactions of Alcohols, Oxidation mechanism
Lecture Organic chemistry: Chapter 15 - L. G. Wade, Jr.
Chapter 15 - Conjugated systems, orbital symmetry, and ultraviolet spectroscopy. In this chapter, we consider the unique properties of conjugated systems, the theoretical reasons for this extra stability, and some of the characteristic reactions of molecules containing conjugated double bonds. We also study ultraviolet spectroscopy, a tool for determining the structures of conjugated systems.
56 p dnulib 27/06/2019 143 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Conjugated system, Orbital symmetry
Lecture Organic chemistry: Chapter 16 - L. G. Wade, Jr.
Chapter 16 introduce to aromatic compounds. This chapter determine whether Hückel’s rule applies to a given structure, and predict whether the compound will be aromatic, antiaromatic, or nonaromatic; show how to construct the molecular orbitals of a conjugated cyclic system similar to benzene and cyclobutadiene;...
59 p dnulib 27/06/2019 167 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Aromatic compounds, Discovery of benzene
Lecture Organic chemistry: Chapter 17 - L. G. Wade, Jr.
Chapter 17 - Reactions of aromatic compounds. In this chapter, we will study several of these reactions and then consider how substituents on the ring influence its reactivity toward electrophilic aromatic substitution and the regiochemistry seen in the products. We will also study other reactions of aromatic compounds, including nucleophilic aromatic substitution, addition reactions, reactions of side chains, and special reactions of phenols.
70 p dnulib 27/06/2019 176 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Aromatic compounds
Lecture Organic chemistry: Chapter 13 - L. G. Wade, Jr.
Chapter 13 - Nuclear magnetic resonance spectroscopy. In this chapter, students will be able to understand: Use the chemical shifts, splitting patterns, and integrations shown in a proton NMR spectrum to propose structures for possible compounds; use the number of peaks and their chemical shifts in a 13C NMR spectrum to determine the number of types of carbon atoms in the compound and what functional groups they might represent;...
71 p dnulib 27/06/2019 212 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Nuclear magnetic resonance, External magnetic field
Lecture Organic chemistry: Chapter 12 - L. G. Wade, Jr.
Chapter 12 - Infrared spectroscopy and mass spectrometry. This chapter identify the reliable characteristic absorptions in an infrared spectrum, and propose which functional groups are likely to be present in the molecule; explain which functional groups cannot be present in a molecule because their characteristic peaks are absent from the IR spectrum; use a mass spectrum to determine a compound’s molecular weight, and propose which elements...
54 p dnulib 27/06/2019 159 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Infrared spectroscopy, Mass spectrometry
Lecture Organic chemistry: Chapter 14 - L. G. Wade, Jr.
Chapter 14 introduce to ethers, epoxides, and sulfides. After completing this chapter, students will be able to: Draw and name ethers and heterocyclic ethers, including epoxides; explain the trends in their boiling points, solubilities, and solvent properties; determine the structures of ethers from their spectra, and explain their characteristic absorptions and fragmentations;...
46 p dnulib 27/06/2019 281 1
Từ khóa: Organic chemistry, Lecture Organic chemistry, Hóa học hữu cơ, Electronic Structure, Hydrogen bond acceptor, Polarity of ethers
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